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Assessing the interplay between the physicochemical parameters of ion-pairing reagents and the analyte sequence on the electrospray desorption process for oligonucleotides
Alkylamines are widely used as ion-pairing agents during LC-MS of oligonucleotides. In addition to a better chromatographic separation, they also assist with the desorption of oligonucleotide ions into the gas phase, cause charge state reduction and decrease cation adduction. However, the choice of...
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| Udgivet i: | J Am Soc Mass Spectrom |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5569388/ https://ncbi.nlm.nih.gov/pubmed/28405940 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-017-1671-6 |
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