Diiron Dithiolate Hydrides Complemented with Proton-Responsive Phosphine–Amine Ligands

The reaction of Fe(2)(pdt)(CO)(6) with two equivalents of Ph(2)PC(6)H(4)NH(2) (PNH(2)) affords the amido hydride HFe(2)(pdt)(CO)(2)(PNH(2))(PNH) {[H1H](0), pdt(2−) = CH(2)(CH(2)S(−))(2)}. Isolated intermediates in this conversion include Fe(2)(pdt)(CO)(5)-(κ(1)-PNH(2)) and Fe(2)(pdt)(CO)(4)(κ(2)-PNH...

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Bibliographic Details
Published in:Eur J Inorg Chem
Main Authors: Carlson, Michaela R., Gilbert-Wilson, Ryan, Gray, Danielle R., Mitra, Joyee, Rauchfuss, Thomas B., Richers, Casseday P.
Format: Artigo
Language:Inglês
Published: 2017
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5553979/
https://ncbi.nlm.nih.gov/pubmed/28808414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201700474
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