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Gear up for a pH shift: a responsive iron(II) 2-amino-6-picolyl-appendent macrocyclic paraCEST agent that protonates at a pendent group

Two high-spin Fe(II) and Co(II) complexes of 1,4,7,10-tetraazacyclododecane (CYCLEN) appended with four 2-amino-6-picolyl groups, denoted as [Fe(TAPC)](2+) and [Co(TAPC)](2+), are reported. These complexes demonstrate C(2)-symmetrical geometry from coordination of two pendents, and they are present...

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Détails bibliographiques
Publié dans:Inorg Chem
Auteurs principaux: Tsitovich, Pavel B., Cox, Jordan M., Spernyak, Joseph A, Morrow, Janet R.
Format: Artigo
Langue:Inglês
Publié: 2016
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5553446/
https://ncbi.nlm.nih.gov/pubmed/27934305
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b02159
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