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Gear up for a pH shift: a responsive iron(II) 2-amino-6-picolyl-appendent macrocyclic paraCEST agent that protonates at a pendent group
Two high-spin Fe(II) and Co(II) complexes of 1,4,7,10-tetraazacyclododecane (CYCLEN) appended with four 2-amino-6-picolyl groups, denoted as [Fe(TAPC)](2+) and [Co(TAPC)](2+), are reported. These complexes demonstrate C(2)-symmetrical geometry from coordination of two pendents, and they are present...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5553446/ https://ncbi.nlm.nih.gov/pubmed/27934305 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b02159 |
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