Manganese–Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts

Incorporation of Mn into an established water oxidation catalyst based on a Co(III)(4)O(4) cubane was achieved by a simple and efficient assembly of permanganate, cobalt(II) acetate, and pyridine to form the cubane oxo cluster MnCo(3)O(4)(OAc)(5)py(3) (OAc = acetate, py = pyridine) (1-OAc) in good y...

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Publicado en:J Am Chem Soc
Main Authors: Nguyen, Andy I., Suess, Daniel L. M., Darago, Lucy E., Oyala, Paul H., Levine, Daniel S., Ziegler, Micah S., Britt, R. David, Tilley, T. Don
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5553203/
https://ncbi.nlm.nih.gov/pubmed/28347135
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01792
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