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Identical active sites in hydroxynitrile lyases show opposite enantioselectivity and reveal possible ancestral mechanism
Evolutionarily related hydroxynitrile lyases from rubber tree (HbHNL) and from Arabidopsis thaliana (AtHNL) follow different catalytic mechanisms with opposite enantioselectivity toward mandelonitrile. We hypothesized that the HbHNL-like mechanism evolved from an enzyme with an AtHNL-like mechanism....
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| Publicado no: | ACS Catal |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5546752/ https://ncbi.nlm.nih.gov/pubmed/28798888 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b01108 |
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