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Transition Metal-Free C3 Arylation of Indoles with Aryl Halides

Herein, we report an unprecedented transition metal-free, coupling of indoles with aryl halides. The reaction is promoted by KOtBu and is regioselective for C3 over nitrogen. The use of degassed solvents devoid of oxygen is necessary for the success of the transformation. Preliminary studies implica...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Chen, Ji, Wu, Jimmy
Format: Artigo
Jezik:Inglês
Izdano: 2017
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5543986/
https://ncbi.nlm.nih.gov/pubmed/28256786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201612311
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