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Transition Metal-Free C3 Arylation of Indoles with Aryl Halides
Herein, we report an unprecedented transition metal-free, coupling of indoles with aryl halides. The reaction is promoted by KOtBu and is regioselective for C3 over nitrogen. The use of degassed solvents devoid of oxygen is necessary for the success of the transformation. Preliminary studies implica...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5543986/ https://ncbi.nlm.nih.gov/pubmed/28256786 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201612311 |
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