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Transition Metal-Free C3 Arylation of Indoles with Aryl Halides
Herein, we report an unprecedented transition metal-free, coupling of indoles with aryl halides. The reaction is promoted by KOtBu and is regioselective for C3 over nitrogen. The use of degassed solvents devoid of oxygen is necessary for the success of the transformation. Preliminary studies implica...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5543986/ https://ncbi.nlm.nih.gov/pubmed/28256786 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201612311 |
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