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Total Synthesis of (+)-Pancratistatin by the Rh(III)-Catalyzed Addition of a Densely Functionalized Benzamide to a Sugar-Derived Nitroalkene
Herein, we report the concise total synthesis of (+)-pancratistatin, accessed in a 10 step linear sequence from commercially available inputs. The convergent synthesis features a highly diastereoselective Rh(III)-catalyzed C-H bond addition to a D-glucose derived nitroalkene and a late stage intramo...
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| Izdano u: | Org Lett |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5541686/ https://ncbi.nlm.nih.gov/pubmed/28537406 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01220 |
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