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Pd-Catalyzed Conjunctive Cross-Coupling Between Grignard-Derived Boron "Ate" Complexes and C(sp(2)) Halides or Triflates: NaOTf as a Grignard Activator and Halide Scavenger
Catalytic enantioselective conjunctive cross-couplings that employ Grignard reagents are shown to furnish an array of non-racemic chiral organoboronic esters in an efficient and highly selective fashion. The utility of sodium triflate in facilitating this reaction is two-fold: it enables "ate&q...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5539536/ https://ncbi.nlm.nih.gov/pubmed/28161943 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b12663 |
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