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Ni-Catalyzed Conversion of Enol Triflates to Alkenyl Halides

A Ni-catalyzed halogenation of enol triflates was developed that enables the synthesis of a broad range of alkenyl iodides, bromides, and chlorides under mild reaction conditions. The reaction utilizes inexpensive, bench stable Ni(OAc)(2)·4H(2)O as a pre-catalyst and proceeds at room temperature in...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Hofstra, Julie L., Poremba, Kelsey E., Shimozono, Alex M., Reisman, Sarah E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7179072/
https://ncbi.nlm.nih.gov/pubmed/31410936
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906815
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