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Vinylidenation of Organoboronic Esters Enabled by a Pd-Catalyzed Metallate Shift.
Organoboron ‘ate’ complexes undergo a net vinyl insertion reaction to give 1,1-disubstituted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst. Reactions that employ vinyllithium afforded good to excellent yields after one hour, while reactions that emplo...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6414219/ https://ncbi.nlm.nih.gov/pubmed/30444946 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201811782 |
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