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Subcomponent Exchange Transforms an Fe(II)(4)L(4) Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System

[Image: see text] Subcomponent exchange transformed new high-spin Fe(II)(4)L(4) cage 1 into previously-reported low-spin Fe(II)(4)L(4) cage 2: 2-formyl-6-methylpyridine was ejected in favor of the less sterically hindered 2-formylpyridine, with concomitant high- to low-spin transition of the cage’s...

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Detaylı Bibliyografya
Yayımlandı:J Am Chem Soc
Asıl Yazarlar: McConnell, Anna J., Aitchison, Catherine M., Grommet, Angela B., Nitschke, Jonathan R.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: American Chemical Society 2017
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5537689/
https://ncbi.nlm.nih.gov/pubmed/28426930
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01478
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