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Temperature Controls Guest Uptake and Release from Zn(4)L(4) Tetrahedra

[Image: see text] We report the preparation of triazatruxene-faced tetrahedral cage 1, which exhibits two diastereomeric configurations (T1 and T2) that differ in the handedness of the ligand faces relative to that of the octahedrally coordinated metal centers. At lower temperatures, T1 is favored,...

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Dades bibliogràfiques
Publicat a:J Am Chem Soc
Autors principals: Zhang, Dawei, Ronson, Tanya K., Güryel, Songül, Thoburn, John D., Wales, David J., Nitschke, Jonathan R.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2019
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6753657/
https://ncbi.nlm.nih.gov/pubmed/31478658
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07307
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