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Mechanistic Model for Enantioselective Intramolecular Alkene Cyanoamidation via Palladium-Catalyzed C–CN Bond Activation
We studied key aspects of the mechanism of Pd-catalyzed C–CN bond activation and intramolecular enantioselective alkene cyanoamidation. An Abboud–Abraham–Kamlet–Taft (AAKT) linear solvation energy relationship (LSER) model for enantioselectivity was established. We investigated the impact of Lewis a...
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| Publicat a: | J Org Chem |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5535300/ https://ncbi.nlm.nih.gov/pubmed/28294618 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b00196 |
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