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Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction
The mechanism of an enantioselective palladium-catalyzed alkene difunctionalization reaction has been investigated. Kinetic analysis provides evidence of turnover limiting attack of a proposed quinone methide intermediate with MeOH and suggests that Cu is involved in productive product formation, no...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2010
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3066298/ https://ncbi.nlm.nih.gov/pubmed/21082845 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108106h |
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