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Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction

The mechanism of an enantioselective palladium-catalyzed alkene difunctionalization reaction has been investigated. Kinetic analysis provides evidence of turnover limiting attack of a proposed quinone methide intermediate with MeOH and suggests that Cu is involved in productive product formation, no...

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Detalhes bibliográficos
Main Authors: Jensen, Katrina H., Webb, Jonathan D., Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3066298/
https://ncbi.nlm.nih.gov/pubmed/21082845
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108106h
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