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A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)(2)M′] Complexes in Oxidation Reactions
The strikingly different reactivity of a series of homo- and heterodinuclear [(M(III))(μ-O)(2)(M(III))(III)](2+) (M = Ni; M′ = Fe, Co, Ni and M = M′ = Co) complexes with β–diketiminate ligands in electrophilic and nucleophilic oxidation reactions is reported, and can be correlated to the spectroscop...
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| 發表在: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2016
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5534222/ https://ncbi.nlm.nih.gov/pubmed/27906528 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201607611 |
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