A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)(2)M′] Complexes in Oxidation Reactions

The strikingly different reactivity of a series of homo- and heterodinuclear [(M(III))(μ-O)(2)(M(III))(III)](2+) (M = Ni; M′ = Fe, Co, Ni and M = M′ = Co) complexes with β–diketiminate ligands in electrophilic and nucleophilic oxidation reactions is reported, and can be correlated to the spectroscop...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Engelmann, Xenia, Yao, Shenglai, Farquhar, Erik R., Szilvási, Tibor, Kuhlmann, Uwe, Hildebrandt, Peter, Driess, Matthias, Ray, Kallol
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2016
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5534222/
https://ncbi.nlm.nih.gov/pubmed/27906528
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201607611
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