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Improved Synthesis for Modular Ascarosides Uncovers Biological Activity

A versatile synthesis of modular ascarosides, a family of signaling molecules from Caenorhabditis elegans and other nematodes, via hydrogenolysis of a cyclic sulfate derived from methyl-α-l-rhamnopyranoside is reported. The route enables selective introduction of different side chains at the 1, 2, a...

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Bibliografiska uppgifter
I publikationen:Org Lett
Huvudupphovsmän: Zhang, Ying K, Sanchez-Ayala, Marco A, Sternberg, Paul W., Srinivasan, Jagan, Schroeder, Frank C.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2017
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5533076/
https://ncbi.nlm.nih.gov/pubmed/28513161
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01009
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