A high-valent non heme μ-oxo Mn(IV) dimer generated from a thiolate-bound Mn(II) complex and O(2)

This study deals with the unprecedented reactivity of dinuclear non heme Mn(II)–thiolate complexes with O(2), which dependent on the protonation state of the initial Mn(II) dimer selectively generates either a di-μ-oxo or μ-oxo-μ-hydroxo Mn(IV) complex. Both dimers have been characterized by differe...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Brazzolotto, Deborah, Cantú Reinhard, Fabián G., Smith-Jones, Julian, Retegan, Marius, Amidani, Lucia, Faponle, Abayomi S., Ray, Kallol, Philouze, Christian, de Visser, Sam P., Gennari, Marcello, Duboc, Carole
Format: Artigo
Idioma:Inglês
Publicat: 2017
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5531755/
https://ncbi.nlm.nih.gov/pubmed/28544340
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703215
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