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Site-selective formation of an iron(iv)–oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines

Iron(iv)–oxo species have been identified as the active intermediates in key enzymatic processes, and their catalytic properties are strongly affected by the equatorial and axial ligands bound to the metal, but details of these effects are still unresolved. In our aim to create better and more effic...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: İşci, Ümit, Faponle, Abayomi S., Afanasiev, Pavel, Albrieux, Florian, Briois, Valérie, Ahsen, Vefa, Dumoulin, Fabienne, Sorokin, Alexander B., de Visser, Sam P.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6088558/
https://ncbi.nlm.nih.gov/pubmed/30155008
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01811k
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