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Diiron oxo reactivity in a weak-field environment
Concomitant deprotonation and metalation of a dinucleating cofacial Pacman dipyrrin ligand platform (tBu)dmxH(2) with Fe(2)(Mes)(4) results in formation of a diiron complex ((tBu)dmx)Fe(2)(Mes)(2). Treatment of ((tBu)dmx)Fe(2)(Mes)(2) with one equivalent of water yields the diiron μ-oxo complex ((tB...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6598509/ https://ncbi.nlm.nih.gov/pubmed/31341583 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00605b |
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