Enantioselective Heck–Matsuda Arylations via Chiral Anion Phase Transfer of Aryl Diazonium Salts

A mild, asymmetric Heck–Matsuda reaction of five-, six- and seven-membered ring alkenes and aryldiazonium salts is presented. High yields and enantioselectivities were achieved using Pd(0) and chiral anion co-catalysts, the latter functioning as a chiral anion phase-transfer (CAPT) reagent. For cert...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Avila, Carolina M., Patel, Jigar S., Reddi, Yernaidu, Saito, Masato, Nelson, Hosea M., Shunatona, Hunter P., Sigman, Matthew S., Sunoj, Raghavan B., Toste, F. Dean
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5528849/
https://ncbi.nlm.nih.gov/pubmed/28418118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201702107
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