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Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: Mn(III) vs Mn(IV) in Biologically Inspired DyMn(3)O(4) Cubanes
Inspired by the ferromagnetic coupling in the cubane model CaMn(IV)(3)O(4) of the oxygen-evolving complex of photosystem II, 3d–4f mixed-metal DyMn(3)O(4) clusters were prepared for investigation of the magnetic properties. For comparison, YMn(IV)(3)O(4) and YMn(IV)(2)Mn(III)O(4) clusters were inves...
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| Опубликовано в: : | Inorg Chem |
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| Главные авторы: | , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2016
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5510600/ https://ncbi.nlm.nih.gov/pubmed/27281290 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b00630 |
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