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Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: Mn(III) vs Mn(IV) in Biologically Inspired DyMn(3)O(4) Cubanes

Inspired by the ferromagnetic coupling in the cubane model CaMn(IV)(3)O(4) of the oxygen-evolving complex of photosystem II, 3d–4f mixed-metal DyMn(3)O(4) clusters were prepared for investigation of the magnetic properties. For comparison, YMn(IV)(3)O(4) and YMn(IV)(2)Mn(III)O(4) clusters were inves...

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Publicado en:Inorg Chem
Main Authors: Lin, Po-Heng, Tsui, Emily Y., Habib, Fatemah, Murugesu, Muralee, Agapie, Theodor
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5510600/
https://ncbi.nlm.nih.gov/pubmed/27281290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b00630
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