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Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides

The enantioselective desymmetrization of cyclic meso-anhydrides with benzyl trifluoroborates under nickel-photoredox catalysis is described. The reaction tolerates a variety of sterically and electronically different trifluoroborates, as well as structurally unique cyclic anhydrides. The trans isome...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Stache, Erin E., Rovis, Tomislav, Doyle, Abigail G.
Format: Artigo
Idioma:Inglês
Publicat: 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5510164/
https://ncbi.nlm.nih.gov/pubmed/28230304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201700097
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