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Distal-Bond-Selective C–C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones
A site-selective rhodium-catalyzed C–C activation of ring-fused cyclopentanones was achieved to afford efficient access to a range of spiroindanones. The use of bulky 2-amino-6-picoline as a cocatalyst is key to the excellent selectivity of this C–C bond cleavage in cyclopentanones.
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5503198/ https://ncbi.nlm.nih.gov/pubmed/28111853 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611642 |
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