Caricamento...
Distal-Bond-Selective C–C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones
A site-selective rhodium-catalyzed C–C activation of ring-fused cyclopentanones was achieved to afford efficient access to a range of spiroindanones. The use of bulky 2-amino-6-picoline as a cocatalyst is key to the excellent selectivity of this C–C bond cleavage in cyclopentanones.
Salvato in:
| Pubblicato in: | Angew Chem Int Ed Engl |
|---|---|
| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2017
|
| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5503198/ https://ncbi.nlm.nih.gov/pubmed/28111853 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611642 |
| Tags: |
Aggiungi Tag
Nessun Tag, puoi essere il primo ad aggiungerne! !
|