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Distal-Bond-Selective C–C Activation of Ring-Fused Cyclopentanones: An Efficient Access to Spiroindanones

A site-selective rhodium-catalyzed C–C activation of ring-fused cyclopentanones was achieved to afford efficient access to a range of spiroindanones. The use of bulky 2-amino-6-picoline as a cocatalyst is key to the excellent selectivity of this C–C bond cleavage in cyclopentanones.

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Xia, Ying, Wang, Jianbo, Dong, Guangbin, Dong, G.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5503198/
https://ncbi.nlm.nih.gov/pubmed/28111853
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611642
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