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One-Pot Enzymatic Total Synthesis of Presteffimycinone, an Early Intermediate of the Anthracycline Antibiotic Steffimycin Biosynthesis
Early acting cyclases play critical roles in programming the polyketide biosynthesis towards certain, distinguished scaffolds. Starting from acetyl-CoA and malonyl-CoA, a one-pot enzymatic total synthesis of an anthracyclinone scaffold, presteffimycinone, was achieved by mixing polyketide synthase (...
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| Udgivet i: | Org Lett |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5502540/ https://ncbi.nlm.nih.gov/pubmed/28102686 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b03708 |
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