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Formation of α-chiral centers by asymmetric β-C(sp(3))-H arylation, alkenylation, and alkynylation
The enzymatic β-C–H hydroxylation of the feedstock chemical isobutytic acid has enabled the asymmetric synthesis of a wide variety of polyketides. The analogous transitionmetal catalyzed enantioselective β-C–H functionalization of isobutyric acid-derived substrates should provide a versatile method...
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| Publicado no: | Science |
|---|---|
| Main Authors: | , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5480404/ https://ncbi.nlm.nih.gov/pubmed/28154075 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aal5175 |
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