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Intra- versus intermolecular electron transfer in radical nucleophilic aromatic substitution of dihalo(hetero)arenes – a tool for estimating π-conjugation in aromatic systems
In this paper, the application of the double radical nucleophilic aromatic substitution (S(RN)1) in various dihalogenated, mostly diiodinated, π-conjugated systems as a tool for qualitatively estimating their π-conjugation is described. This approach uses electron delocalisation as a measure of π-co...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5436300/ https://ncbi.nlm.nih.gov/pubmed/28580099 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00100b |
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