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Intra- versus intermolecular electron transfer in radical nucleophilic aromatic substitution of dihalo(hetero)arenes – a tool for estimating π-conjugation in aromatic systems

In this paper, the application of the double radical nucleophilic aromatic substitution (S(RN)1) in various dihalogenated, mostly diiodinated, π-conjugated systems as a tool for qualitatively estimating their π-conjugation is described. This approach uses electron delocalisation as a measure of π-co...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Janhsen, B., Daniliuc, C. G., Studer, A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5436300/
https://ncbi.nlm.nih.gov/pubmed/28580099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00100b
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