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Transetherification on Polyols by Intra- and Intermolecular Nucleophilic Substitutions

Transetherification on polyols involving intra- and intermolecular nucleophilic substitutions is reported. Di- or trialkoxide formation of propane-1,3-diol or 2-(hydroxymethyl)propane-1,3-diol derivatives by NaH triggers the reaction via oxetanes formation, where the order to add NaH and a polyol si...

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Autors principals: Muraoka, Takahiro, Adachi, Kota, Chowdhury, Rainy, Kinbara, Kazushi
Format: Artigo
Idioma:Inglês
Publicat: Public Library of Science 2014
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3963852/
https://ncbi.nlm.nih.gov/pubmed/24663293
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1371/journal.pone.0091912
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