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The influence of acceptor nucleophilicity on the glycosylation reaction mechanism
A set of model nucleophiles of gradually changing nucleophilicity is used to probe the glycosylation reaction mechanism. Glycosylations of ethanol-based acceptors, bearing varying amounts of fluorine atoms, report on the dependency of the stereochemistry in condensation reactions on the nucleophilic...
Tallennettuna:
| Julkaisussa: | Chem Sci |
|---|---|
| Päätekijät: | , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
Royal Society of Chemistry
2017
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5424809/ https://ncbi.nlm.nih.gov/pubmed/28553477 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04638j |
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