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Stereoselective cis-Vinylcyclopropanation via a Gold(I)-Catalyzed Retro-Buchner Reaction under Mild Conditions
[Image: see text] A highly stereoselective gold(I)-catalyzed cis-vinylcyclopropanation of alkenes has been developed. Allylic gold carbenes, generated via a retro-Buchner reaction of 7-alkenyl-1,3,5-cycloheptatrienes, react with alkenes to form vinylcyclopropanes. The gold(I)-catalyzed retro-Buchner...
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| Publicado en: | ACS Catal |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American
Chemical Society
2017
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5424441/ https://ncbi.nlm.nih.gov/pubmed/28503355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b00737 |
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