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Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates
[Image: see text] Cycloisomerizations of 1,n-enynes catalyzed by gold(I) proceed via electrophilic species with a highly distorted cyclopropyl gold(I) carbene-like structure, which can react with different nucleophiles to form a wide variety of products by attack at the cyclopropane or the carbene c...
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| Udgivet i: | J Org Chem |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2015
|
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4531321/ https://ncbi.nlm.nih.gov/pubmed/26061916 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01106 |
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