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Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates

[Image: see text] Cycloisomerizations of 1,n-enynes catalyzed by gold(I) proceed via electrophilic species with a highly distorted cyclopropyl gold(I) carbene-like structure, which can react with different nucleophiles to form a wide variety of products by attack at the cyclopropane or the carbene c...

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Bibliografiset tiedot
Julkaisussa:J Org Chem
Päätekijät: Dorel, Ruth, Echavarren, Antonio M.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: American Chemical Society 2015
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4531321/
https://ncbi.nlm.nih.gov/pubmed/26061916
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01106
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