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Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations
Lower Lewis acidity boranes demonstrate greater tolerance to combinations of water/strong Brønsted bases than B(C(6)F(5))(3), this enables Si−H bond activation by a frustrated Lewis pair (FLP) mechanism to proceed in the presence of H(2)O/alkylamines. Specifically, BPh(3) has improved water toleranc...
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| 出版年: | Chemistry |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5396349/ https://ncbi.nlm.nih.gov/pubmed/27977048 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201605466 |
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