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BCl(3)‐Induced Annulative Oxo‐ and Thioboration for the Formation of C3‐Borylated Benzofurans and Benzothiophenes

BCl(3)‐induced borylative cyclization of aryl‐alkynes possessing ortho‐EMe (E=S, O) groups represents a simple, metal‐free method for the formation of C3‐borylated benzothiophenes and benzofurans. The dichloro(heteroaryl)borane primary products can be protected to form synthetically ubiquitous pinac...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Warner, Andrew J., Churn, Anna, McGough, John S., Ingleson, Michael J.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2016
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5396270/
https://ncbi.nlm.nih.gov/pubmed/27897368
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201610014
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