Enantioselective Synthesis of (−)-Acetylapoaranotin

[Image: see text] The first enantioselective total synthesis of the epipolythiodiketopiperazine (ETP) natural product (−)-acetylapoaranotin (3) is reported. The concise synthesis was enabled by an eight-step synthesis of a key cyclohexadienol-containing amino ester building block. The absolute stere...

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Udgivet i:Org Lett
Main Authors: Wang, Haoxuan, Regan, Clinton J., Codelli, Julian A., Romanato, Paola, Puchlopek-Dermenci, Angela L. A., Reisman, Sarah E.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2017
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5387676/
https://ncbi.nlm.nih.gov/pubmed/28349698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00418
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