Loading...
Enantioselective Total Synthesis of (−) - Acetylaranotin, A Dihydrooxepine Epidithiodiketopiperazine
The first total synthesis of the dihydrooxepine-containing epidithiodiketopiperazine (ETP) (−)-acetylaranotin (1) is reported. The key steps of the synthesis include an enantioselective azomethine ylide (1, 3)-dipolar cycloaddition reaction to set the absolute and relative stereochemistry, a rhodium...
Na minha lista:
| Main Authors: | , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
|
| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3271125/ https://ncbi.nlm.nih.gov/pubmed/22023250 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja209354e |
| Tags: |
Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
|