The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes

A mild palladium-catalyzed ligand-controlled regioselective 1,3-arylfluorination of 2[H]-chromenes has been developed. The products with a syn-1,3 substitution pattern were obtained with high enantiomeric excess using a PyrOx ligand, wherein the utility of these pyranyl-fluorides was further demonst...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Thornbury, Richard T., Saini, Vaneet, Fernandes, Talita de A., Santiago, Celine B., Talbot, Eric P. A., Sigman, Matthew S., McKenna, Jeffrey M., Toste, F. Dean
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2017
Pynciau:
Chemistry
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5376715/
https://ncbi.nlm.nih.gov/pubmed/28451354
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05102b
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