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Symmetry in Cascade Chirality-Transfer Processes: A Catalytic Atroposelective Direct Arylation Approach to BINOL Derivatives
Herein we disclose a scalable organo-catalytic direct arylation approach for the regio- and atroposelective synthesis of non-C(2)-symmetric 2,2′-dihydroxy-1,1′-binaphthalenes (BINOLs). In the presence of catalytic amounts of axially chiral phosphoric acids, phenols and naphthols are coupled with imi...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5360188/ https://ncbi.nlm.nih.gov/pubmed/27052566 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01458 |
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