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Excited-State Proton Transfer in Chiral Environments: Photoracemization of BINOLs1
We have studied excited-state proton transfer (ESPT) from chiral proton donors to chiral and achiral acceptors. The key role of the exergonicity of the reaction and the transition-state position along the reaction coordinate for the existence of an enantiomeric effect was established. This effect wa...
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| Autors principals: | , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2756819/ https://ncbi.nlm.nih.gov/pubmed/20046928 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1560/IJC.49.2.227 |
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