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Iminophosphanes: Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles

[Image: see text] Highly stable iminophosphanes, obtained from alkylating nitriles and reaction of the resulting nitrilium ions with secondary phosphanes, were explored as tunable P-monodentate and 1,3-P,N bidentate ligands in rhodium complexes. X-ray crystal structures are reported for both κ(1) an...

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Detalhes bibliográficos
Publicado no:Organometallics
Main Authors: Rong, Mark K., van Duin, Koen, van Dijk, Tom, de Pater, Jeroen J. M., Deelman, Berth-Jan, Nieger, Martin, Ehlers, A. W., Slootweg, J. Chris, Lammertsma, Koop
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5350608/
https://ncbi.nlm.nih.gov/pubmed/28316361
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00057
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