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A Structure-Based Mechanism for Oxidative Decarboxylation Reactions Mediated by Amino Acids and Heme Propionates in Coproheme Decarboxylase (HemQ)
Coproheme decarboxylase catalyzes two sequential oxidative decarboxylations with H(2)O(2) as the oxidant, coproheme III as substrate and cofactor, and heme b as the product. Each reaction breaks a C-C bond and results in net loss of hydride, via steps that are not clear. Solution and solid-state str...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5348300/ https://ncbi.nlm.nih.gov/pubmed/27936663 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11324 |
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