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Synthesis of 2‐Alkynoates by Palladium(II)‐Catalyzed Oxidative Carbonylation of Terminal Alkynes and Alcohols

A homogeneous Pd(II) catalyst, utilizing a simple and inexpensive amine ligand (TMEDA), allows 2‐alkynoates to be prepared in high yields by an oxidative carbonylation of terminal alkynes and alcohols. The catalyst system overcomes many of the limitations of previous palladium carbonylation catalyst...

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Bibliografische gegevens
Gepubliceerd in:Chemistry
Hoofdauteurs: Cao, Qun, Hughes, N. Louise, Muldoon, Mark J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: John Wiley and Sons Inc. 2016
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5347984/
https://ncbi.nlm.nih.gov/pubmed/27305489
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201602558
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