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Total Synthesis of (−)-Spinosyn A via Carbonylative Macrolactonization
Spinosyn A (1), a complex natural product featuring a unique 5,6,5,12-fused tetracyclic core structure, is the major component of spinosad, an organic insecticide and an FDA-approved agent used worldwide. Herein, we report an efficient total synthesis of (−)-spinosyn A with 15 steps in the longest l...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5322741/ https://ncbi.nlm.nih.gov/pubmed/27510806 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b07585 |
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