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Nickel pincer model of the active site of lactate racemase involves ligand participation in hydride transfer
Lactate racemase is the first enzyme known to possess a metal pincer active site. The enzyme interconverts d- and l-lactic acid, which is important for the assembly of cell walls in many microorganisms. Here, we report a synthetic model of the active site of lactate racemase, which features a pyridi...
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| Udgivet i: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5307482/ https://ncbi.nlm.nih.gov/pubmed/28115700 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1616038114 |
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