Llwytho...
On the origin of the stereoselectivity in chiral amide-based ammonium ylide-mediated epoxidations
ABSTRACT: Detailed DFT studies provide an in-depth mechanistic understanding for the use of chiral amide-based ammonium ylides in epoxidation reactions. It is shown that the used chiral auxiliary efficiently shields one face of the ylide, which thus results in an extraordinarily high stereoselectivi...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Monatsh Chem |
|---|---|
| Prif Awduron: | , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
Springer Vienna
2016
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5225234/ https://ncbi.nlm.nih.gov/pubmed/28127093 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-016-1866-8 |
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